How do you measure the angle between two surfaces?
Place the phone flat on the first surface and tap Set reference. The dashed arm stays in that position and the reading returns to zero.
Move the phone to the second surface, keeping it the same way round. The number now shows the angle between the two surfaces.
A level can only measure against gravity. That does not help when both surfaces are already tilted.
Choosing your own zero position is what a sliding bevel does. That is why this page has Set reference where the other tools have Calibrate.
How do you work out a mitre cut?
Divide the reading by two. Each of the two pieces takes half of the angle, so a 92° corner needs two cuts of 46°, not 45°.
Note that the reading is the angle you turned through, not the angle of the corner itself.
An internal corner is 180° minus the reading. An external corner is 180° plus the reading.
If the phone has to go somewhere you cannot see the screen, tap Hold first. The number stays fixed until you tap it again.